郑州大学化学与分子工程学院导师：牛云垠 正文

　　
　　姓名：牛云垠　　性别：男　　　出生年月：1960年
　　职称：教授　　学院：化学与分子工程学院　最后学历：博士
　　主要研究方向：超分子，无机金属聚合物，原子簇聚合物结构与性能的关系
　　
　　牛云垠, 男，42岁，理学博士，教授，河南省高等学校骨干教师，郑州大学骨干教师，硕士研究生导师，河南省学术技术带头人, 郑州大学引进人才优秀个人。1992-1995年在郑州大学化学系攻读硕士学位,从事二茂铁酰腙类配合物的合成；1999-2002在南京大学化学系攻读博士学位。主要从事原子簇类化合物的合成与三阶非线性光学性能研究；2002-至今在郑州大学化学系工作，主要研究工作为超分子，无机金属聚合物，原子簇聚合物结构与性能的关系。

　　九年来共主持2项国家自然科学基金，主持1项河南省杰出青年基金，主持1项中国博士后科学基金；并获1项河南省科技进步二等奖，1项河南省自然科学优秀论文一等奖，2项二等奖。 1997年至今，先后在国内外知名刊物发表学术论文58篇，其中SCI论文51篇，核心期刊6篇，截止到2010年底，总的被引用次数超过165次。并为国际期刊Dalton Trans, Cryst. Growth Des., CrystEngComm, New J. Chem., J. Solid State Chem.等的审稿人。Global J. Inorg. Chem.编委，University of Malaya博士论文External Examiner, 申请和参与发明专利各一项。合作出版专著2部。

　　主持项目：
　　(i) 国家自然科学基金，以多氮杂环阳离子为模板的过渡金属簇合物互穿体系的定向构筑及性能研究（21171148），2012.1.-2015.12。
　　(ii) 国家自然科学基金，新型原子簇及其配位聚合物与凝胶玻璃复合的光学功能型材料的设计、合成（20671083），2007.1.-2009.12。
　　(iii) 河南省杰出青年基金，利用有机多吡啶配体构筑原子簇聚合物的精细因素研究(0612002800），2006-2008。
　　(iv) 河南省自然科学基金，有机不对称配体构筑的原子簇聚合物及性能研究（511022700），2005.1－2006.12.
　　(v) 河南省骨干教师项目，阳离子调节型金属超分子聚合物的合理合成， 2009-2010。
　　(vi) 南京大学配位化学重点实验室开放研究基金。2012.1-2013.12

　　省部级奖励：
　　1．《有机不对称配体构筑的原子簇聚合物及性能研究》，获河南省科学技术进步二等奖，牛云垠*，朱路，朱玉，刘修存，王庆丽，郭晓玲，赵付凯. 河南省人民政府，2007.11。
　　2．《含硫杂金属原子簇聚合物》，获河南省第九届自然科学优秀学术论文一等奖，牛云垠*，赵付凯，王庆丽，刘修存，河南省科技厅，河南省科协，2006.6.

　　编写专著：
　　(i).《低热固相化学反应》，普通高等教育“十一五”国家级规划教材，忻新泉，周益明，牛云垠编著，高等教育出版社。2010.7. ISBN 978-7-04-028695-3.
　　(ii). A Systematic Design and Facile Construct of Tetraphenylborate Salt Supramoleculer Polymers with 1, ω-bis(pyridinium)Alkanes Dications. Advances in Materials Science Research. Volume 6, Fu-Kai Zhao, Xiu-Cun Liu, Yun-Yin Niu,* Dong-Hui Wei, Hong-Wei Hou, Ming-Sheng Tang, Yao-Ting Fan, Yu Zhu. Nova Science Publishers, 2011. Volume 6, v.6. 213, 30

　　申请专利：
　　(i)．一种多钼酸化合物及其制备方法， 牛云垠,* 吕效锐，侯红卫，国家发明专利，专利号ZL 200810140503.3.已授权。
　　(ii)．氟康唑配位聚合物、制备方法及用途。侯红卫,* 韩华云，樊耀亭，孟祥茹，牛云银， 200410010159.8, 国家发明专利，0150703064。已授权

　　发表主要论文
　　1. Yong-Zhen Qiao, Jun-Ming Yue, Xiu-Cun Liu and Yun-Yin Niu.* Three novel cation-templated metal thiocyanates with 1-2D polypseudorotaxane frameworks. CrystEngComm, 2011, 13, 6885-6892.
　　2. Jun-Ming Yue, Yun-Yin Niu,* Bing Zhang, Seik-Weng Ng and Hong-Wei Hou. “Four novel metal coordination polymers directed by 1,1′-dibutyl-4,4′-bipyridinium dibromide (BBP) and their framework dependent luminescent properties.” CrystEngComm. 2011, 13(7), 2571-2577.
　　3. Niu, Yun-Yin;* Wang, Ling-Fang; Lv, Xiao-Rui; Du, Hai-Juan; Qiao, Yong-Zhen; Wang, Hong-Mei; Song, Li-Sha; Wu, Ben-Lai; Hou, Hong-Wei; Ng, Seik Weng. Construction and isomeric transformation of polyoxometalates directed by 1, w-bis(pyridinium)alkane templates. CrystEngComm. 2011, 13(16), 5071-5081.
　　4. Han, Yi; Zhang, Zhenhua; Liu, Yanyan; Niu, Yunyin;* Ding, Degang; Wu, Benlai; Hou, Hongwei;* Fan, Yaoting. External Template-Assisted Self-Assembly:Design and Synthesis of 4,4'-bipy-Based Mo(W)/Cu/S Heterothiometallic Polymeric Clusters Directed by 1,1'-Bis(pyridinium)methylene Cation. Cryst. Growth Des. 2011, 11(8), 3448-3455.
　　5. Zhen-Hua Zhang, Hong-Mei Wang, Yun-Yin Niu,* Ben-Lai Wu, Seik-Weng Ng, Hong-Wei Hou. Design and the cation-templated self-assembly on the [MoOS3Cu3]+ based supramolecular polymeric clusters. Inorg. Chem. Commun. 2011, 14, 1783–1787.
　　6. Zhenhua Zhang; Yunyin Niu;* Seikweng Ng; Benlai Wu; HongWei Hou. Template construction of a series of supramolecular coordination polymers via 6,7-dihydro-5H-[1,4]diazepino[1,2,3,4-lmn][1,10]phenanthroline-4,8-diium cation. J. Coord. Chem. 2011, 64(10), 1683–1694.
　　7. Jun-Ming Yue, Na Xu, Zhen-Hua Zhang, Wen-Long Dong, Yun-Yin Niu,* Hong-Wei Hou. Role of spacers and substituents in the self-assembly process: Syntheses and characterization of two novel thiocyanatocuprates polymers. Inorg. Chem. Commun. 2010, 13, 1534–1537.
　　8. Yun-Yin Niu,* Ben-Lai Wu, Qing-Li Wang, Xiao-Ling Guo, Hong-Yun Zhang, Hong-Wei Hou, Yi Han, Ling-Fang Wang. “Construction of 1–2D CuI(or CuII) metal–organic architectures with metal thiocyanates and bipyridyl spacers: Syntheses, structures, and thermal properties.” Inorg. Chim. Acta. 2009, 362, 556–562.
　　9. Xiao-Rui Lv, Fu-Kai Zhao, Xiao-Ling Guo, Yun-Yin Niu*, Na Xu, Hong-Wei Hou,Yao-Ting Fan, Dong Sun, Yu Zhu. Hydrothermal synthesis, structure and fluorescent property of a novel cuprous thiocyanate inorganic polymer directed by 1,5-bis(pyridinium) pentane cation. Inorg. Chem. Commun. 2009，12，653–656.
　　10. Yun-Yin Niu,* Ben-Lai Wu, Xiao-Ling Guo, Ying-Lin Song, Xiu-Cun Liu,Hong-Yun Zhang, Hong-Wei Hou, Cao-Yuan Niu, And Seik-Weng Ng. “A Systematic Design And Facile Construct Of Metal Pseudohalide Frameworks Directed By 1,Ω-Bis(Pyridinium)Alkane Cations.” Cryst. Growth Des. 2008, 8, 2393–2401.
　　11. Ping Zhang, Yun-Yin Niu*, Ben-Lai Wu, Hong-Yun Zhang*, Cao-Yuan Niu, Hong-Wei Hou. 2D frameworks of Cu(II) and Zn(II) organo-metallic polymers self-assembled with N,N'-(1,2-phenylene)diisonicotinamide: Syntheses, structures, photoluminescence, and thermal properties. Inorg. Chim. Acta. 2008, 361, 2609–2615.
　　12. Yunyin Niu, Ning Zhang, Hongwei Hou,* Yu Zhu, Mingsheng Tang and Seik Weng Ng Adaptable metal cluster block: Facile construction of photoluminescent CuI coordination polymeric clusters with metal (I) iodides. J. Mol. Struct. 2007，827，195-200.
　　13. Yunyin Niu, Yinglin Song, Ning Zhang, Hongwei Hou,* Deji Che, Yaoting Fan, Yu Zhu, Chunying Duan, “Reactivity of Polyiodides toward 1, 3-Bis(4-Pyridyl)Propane (bpp): a New CuI Cluster Polycatenane Framework and a Novel 2D AgI Cluster Motif.”Eur. J. Inorg. Chem, 2006, 11，2259-2267.
　　14. Yunyin Niu*, Zhongjun Li, Yinglin Song, Mingsheng Tanga, Benlai Wu, Xinquan Xin. “Three-dimensional molecular network, [{Cu(dps)2(SO4)} × 3H2O×DMF]n, and its different third-order NLO performance (dps = 4,4’-dipyridyl sulfide).” J. Solid State Chem.，2006，179，4003-4010.
　　15. Yunyin Niu*, Yinglin Song, Qingli Wang, Xiaoling Guo, Yu Zhu and Hongwei Hou. “Synthesis, Crystal Structure, and Optical Limiting Effect of a Cu(I) Coordination Polymeric Cluster Bridged by Chiral-carbon Skeleton Bipyridyl Ligand”. Chem. Lett. 2006, 35 (6), 650-651.
　　16. Yunyin Niu, Yinglin Song, Hongwei Hou,* Yu Zhu. “Synthesis, Structure and Large Optical Limiting Effect of the First Coordination Polymeric Cluster Based on {I@[AgI(inh)]6} Hexagram Block.” Inorg. Chem. 2005, 44(7), 2553-2556.
　　17. Yunyin Niu, Ning Zhang , Yinglin Song , Hongwei Hou,* Yaoting Fan , Yu Zhu. “The syntheses, crystal structures and optical limiting effects of transition metal complexes bridged by bipyridyl-based ligands.” Inorg. Chem. Commun. 2005, 8，495-457.
　　18. Yunyin Niu, Hegen Zheng, Hongwei Hou, Xinquan Xin.* “Heterothiometallic polymeric clusters”. Coord. Chem. Rev. 2004, 248, 169-192.
　　19. Yun-Yin Niu, Ying-Lin Song, Jie Wu,Hongwei Hou,* and Yu Zhu. “Nonlinear polymeric effect: synthesis, crystal structure and nonlinear optical properties of a new mercury iodide adduct polymer [Hg(bpfb)I2]n×2DMF (bpfb = N,N’-bis(4-pyridyl formamide)-1,4-benzene)” Inorg. Chem. Commun. 2004, 7, 471-474.
　　20. Ying-Lin Song, Yun-Yin Niu, Hong-Wei Hou,* Yu Zhu.“The synthesis, crystal structure and optical limiting properties of ZnI2-pyrazine adduct polymer linked by iodine···iodine supramolecular soft-soft interaction.” J. Mol. Struct. 2004, 689/1-2, 69-74.
　　21. Yunyin Niu, Yinglin Song, Hegen Zheng, Feng Li, Hoongkun Fun and Xinquan Xin,* “The first heterothiometallic complex of [N(SPPh2)2]-: Synthesis, structure and nonlinear optical effect of dodecanuclear cluster {[Et4N]4 Mo4Cu­4S12O4[Cu(NSPPh2)2]4}”, New J. Chem. 2001, 257, 945-948.
　　22. Qianfeng Zhang, Yunyin Niu, W. H. Leung, Yinglin Song, Ian D. Williams Xinquan Xin.* “Synthesis of a 2D polymeric cluster {[NEt4][Mo2O2S6Cu6 I3 (4,4-bipy)5]·MeOH·H2O}n with a significant improvement of optical limiting effect.” Chem. Commun., 2001, 1126-1127.
　　23. Yunyin Niu, Tian Niu Chen, Shixiong Liu, Yinglin Song, Yu Xiao Wang, Ziling Xue, Xinquan Xin.* “Reactivity of the [MoS4Cu6Br8]4- anion toward polyarylphosphorus ligands: synthesis, characterization and nonlinear optical properties of [MoS4(Cudppf)2]·2DMF·CH3CN and [MoS4Cu2(Ph2PPy)4] [dppf = 1, 1-bis (diphenylphosphino)ferrocene; Ph2PPy = 2-(diphenylphosphino) pyridine]” ，J. Chem. Soc., Dalton Trans., 2002, 1980–1984.
　　24. Yunyin Niu, Hongwei Hou, * Yongli Wei, Yaoting Fan, Yu Zhu, Chenxia Du & Xinquan. Xin. “A Linear Piperazine-Pyridine Ligand and Its Hg Coordination Polymer”, Inorg. Chem. Commun. 2001, 4(7), 358-361.
　　25. Yunyin Niu, Yuxiao Wang, Yinglin Song, Shixiong Liu, Hegen Zheng, Xinquan Xin.* ”synthesis, structure and optical refractive effect of dibutyltin(IV) complex of [Ph2P(S)NP(S)Ph2]- .” Chem. Lett., 2001, 1004-1005.
　　26. Yunyin Niu, Yinglin Song , Shixiong Liu, and Xinquan Xin. “ Synthesis, crystal structure and large nonlinear refractive properties of mercury iodide adduct with 1,1-bis(diphenylphosphino) ferrocene.” Z. Anorg. Allg. Chem. 2002, 628, 179-182.
　　27. Yunyin Niu, Yinglin Song, Tianniu Chen, Ziling Xue, Xinquan Xin.* “A novel HgI2 adduct with bipyridyl ligand: synthesis, structure and optical refractive effect of [HgI2(4,4-azobipyridine)]n”, CrystEngComm, 2001, 36, 1-3.

　　联系方式:Email: niuyy@zzu.edu.cn QQ: 642988550
　　通讯地址: College of Chemistry and Molecular Engineering, Zhengzhou University, 75 Daxue Road, Zhengzhou 450052, China

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